Chlorido{2-[(dimethylamino)methyl]phenyl-κ2 C 1,N}(1-methyl-1H-imidazole-κN 3)palladium(II)
نویسندگان
چکیده
In the title compound, [Pd(C(9)H(12)N)Cl(C(4)H(6)N(2))], which was synthesized from the reaction of 1-methyl-imidazole with dimeric dichloridobis[2-(dimethyl-amino)-benz-yl]palla-dium(II), the ring-deprotonated N,N-dimethyl-benzyl-amine ligand acts in a C,N-bidentate fashion. The dihedral angle between the ring of the 1-methyl-imidazole ligand and the palladacycle plane is 57.88 (16)°. The two N atoms from the N,N-dimethyl-benzyl-amine and 1-methyl-imidazole ligands are trans coordinated to the Pd(II) atom.
منابع مشابه
Chlorido(1,2-dimethyl-1H-imidazole-κN 3){2-[(diphenoxyphosphanyl)oxy]phenyl-κ2 C 1,P}palladium(II)
The Pd atom in the title compound, [Pd(C(18)H(14)O(3)P)Cl(C(5)H(8)N(2))], adopts a slightly distorted square-planar coordination geometry, with the metallated carbon positioned trans to the Cl atom. The crystal structure is stabilized by several weak C-H⋯O and C-H⋯Cl hydrogen-bond inter-actions. One of the phenyl rings is disordered over two almost equally occupied sites.
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